Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS     

Kaj Sullivan  Daniel Layton‐Matthews  Matthew Leybourne  James Kidder  Zoltn Mester  Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.  相似文献   

Middle Permian organic carbon isotope stratigraphy and the origin of the Kamura Event     

《Gondwana Research》2020

Large carbon cycle perturbations associated with the Middle Permian (Capitanian) mass extinction have been widely reported, but their causes and timing are still in dispute. Low resolution carbon isotope records prior to this event also limit the construction of a Middle Permian chemostratigraphic framework and global or local stratigraphic correlation, and hence limit our understanding of carbon cycle and environmental changes. To investigate these issues, we analyzed the ¹³C_org values from the Middle Permian chert-mudstone sequence (Gufeng Formation) in the Lower Yangtze deep-water basin (South China) and compared them with published records to build a chemostratigraphic scheme and discuss the underlying environmental events. The records show increased δ¹³C_org values from late Kungurian to early Guadalupian, followed by a decrease to the late Wordian/early Capitanian. The early-mid Capitanian was characterized by elevated δ¹³C_org values suggesting the presence of the “Kamura Event”: an interval of heavy positive values seen in the δ¹³C_carb record. We propose that these heavy Capitanian δ¹³C values may be a response to a marked decline in chemical weathering rates on Pangea and associated reduction in carbonate burial, which we show using a biogeochemical model. The subsequent negative δ¹³C excursion seen in some carbonate records, especially in shallower-water sections (and in a muted expression in organic carbon) coincide with the Capitanian mass extinction may be caused by the input of isotopically-light carbon sourced from the terrestrial decomposition of organic matter.  相似文献   

基于多元统计分析的渔山列岛潮间带软体动物功能群和次级生产力比较   总被引：1，自引：0，他引：1  

徐鹏  刘好真  刘懂  焦海峰  王一农  尤仲杰 《海洋与湖沼》2018,49(1):151-159

渔山列岛于2008年成为国家级海洋生态保护区,为了解渔山列岛保护区内潮间带软体动物次级生产力的时空变化。于1982年和2010年的3个季节(春、夏、冬)在渔山列岛进行潮间带软体动物调查,采用多元统计分析软体动物时空差异,以Brey经验公式计算分析软体动物次级生产力(P值,P/B值)。结果表明,年际间物种食性结构发生了明显的改变,1982年潮间带软体动物对次级生产力贡献率最大的物种有单齿螺(Monodonta labio)、锈凹螺(Chlorostoma rustica),占软体动物总次级生产力的42.88%,2010年潮间带软体动物对次级生产力贡献率最大的物种有覆瓦小蛇螺(Serpulorbis imbricata)、条纹隔贻贝(Septifer virgatus),占软体动物总次级生产力的75.96%。1982年,年均栖息密度为2758ind/m2,年均生物量为2100.26g/m2,年均次级生产力为240.04g/(m2·a),年均P/B值为0.63a–1;2010年,年均栖息密度为699ind/m2,年均生物量为1101.85g/m2,年均次级生产力为94.82g/(m2·a),年均P/B值为0.55a–1。多因素方差分析表明软体动物次级生产力年际间差异显著(F=5.761,P0.05),季节间和潮位间差异都不显著(F=0.135,P0.05;F=2.076,P0.05),P/B的值较低,表明该海域软体动物世代更替速度较慢,2010年的P/B值(0.55a–1)低于1982年的P/B值(0.63a–1),表明近30年来群落结构受到影响。  相似文献   

小跨高比带楼板半通缝连梁抗震性能有限元分析          下载免费PDF全文

张超  陈向上  于德湖 《世界地震工程》2018,34(1):051-62

为了缓解联肢剪力墙中小跨高比连梁发生低延性的剪切破坏，增强连梁的变形和耗能能力，可在单连梁中轴线位置设置半通缝并配置交叉斜筋，形成半通缝连梁。本文完成了的对7种连梁的模拟，分析了在小跨高比、低周反复荷载作用条件下不同类型带楼板连梁的承载力、变形能力、刚度退化和耗能能力以及不同跨高比、不同开缝位置对带楼板半通缝连梁抗震性能的影响。结果表明:楼板会使半通缝连梁的剪压比增大，延性下降；但相比于普通连梁和双连梁，半通缝连梁具有较好的变形能力和承载力，可在实际中推广。  相似文献   

海洋气团对沿海城市大气环境影响与识别研究     

石红旗  王霄曈  张昊阳  石博欣  张睿 《海洋科学》2018,42(12):100-108

本研究通过识别海洋气团特征及沿海城市大气受到海洋气团的影响方式与程度,为评价沿海城市空气环境质量提供科学依据。以青岛市为例,收集大气气溶胶样品中放射性核素~(210)Pb、40K数据及采集时段当地大气颗粒物数据;分析~(210)Pb活度浓度与气溶胶颗粒物浓度变化;对当地当时大气气团进行溯源分析。研究表明:(1)研究期间青岛沿岸地区2015年4月至2016年6月与2016年6月至2017年6月大气污染特征显著不同,前者~(210)Pb活度浓度与污染颗粒物浓度显著相关,而后者~(210)Pb活度浓度与污染颗粒物无相关关系;(2)穿越海洋的陆地气团呈现出高活度浓度、低颗粒物浓度的特征;来自海洋气团的气溶胶呈现出低活度浓度、低颗粒物浓度的特征;(3)海洋气团气溶胶中~(210)Pb活度浓度较低。临近大陆的海洋(黄海、东海)上层大气受到大陆气团的影响,其海洋气团的特征有所减弱。~(210)Pb活度浓度、颗粒物浓度(PM2.5)可作为判断海洋气团的指标,识别"来自海洋的气团"与"经过海洋的气团"。  相似文献   

下扬子及周边地区深部泊松比结构及深部动力过程约束研究   总被引：1，自引：0，他引：1       下载免费PDF全文

张昌榕  张贵宾  江国明  吕庆田  徐峣 《地球物理学报》2018,61(11):4418-4435

下扬子及周边地区存在着丰富的地质构造和多金属矿产资源，其深部结构和动力学过程已成为地学界研究的热点.为了更好地讨论下扬子及周边地区的深部动力学过程和岩浆活动机制，本文基于均匀网格层析成像方法提出了非均匀网格远震层析成像方法，利用大量的天然地震相对走时残差数据反演获得了下扬子及周边地区深至700 km范围内的三维S波和P波速度结构，并根据纵横波的比值关系计算出泊松比异常.由于S波速度比P波对流体的反应更加敏感，所以泊松比异常反映了物质是否包含流体或者物质的软硬、冷热程度.本研究结果显示：（1）长江中下游成矿带下方的上地幔内存在明显的高泊松比异常，而地幔过渡带内则存在明显的低泊松比异常；（2）大别造山带及其南侧的中扬子地块的上地幔中下部及地幔过渡带内都存在明显低泊松比异常，且呈现东深西浅的空间分布特征.结合已有的地质、地球物理和地球化学等资料，我们认为长江中下游成矿带下方的地幔过渡带内滞留着古太平洋俯冲板块，其上地幔内则赋存着软的上地幔热物质，为深部成矿提供了热量或幔源物质.因此，古太平洋板块的俯冲对长江中下游成矿带的形成发挥了至关重要的作用.  相似文献   

黄土河谷场地地形放大效应的研究     

王良  卢育霞  马林伟  孔德政 《大地测量与地球动力学》2018,38(2):167-171

使用黄土河谷场地模型对地震动峰值加速度和频谱特征进行研究。结果表明，不同工况下各观测点PGA的放大比呈现出不同的变化规律。分析山顶和山谷各点的傅里叶谱以及谱比发现，在地形和土层共同作用下的放大效应是各自单独作用下放大效应的乘积。  相似文献   

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N   总被引：1，自引：0，他引：1  

荣坤波  曾志刚  殷学博  陈帅  王晓媛  齐海燕  马瑶 《海洋学报(英文版)》2018,37(9):67-81

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.  相似文献   

The bivalve Lembulus bicuspidatus may enhance denitrification in shelf sediment at the Angola–Benguela Frontal Zone     

A Neumann  A Flohr 《African Journal of Marine Science》2018,40(1):91-96

We collected living individuals of the bivalve Lembulus bicuspidatus, which shows an unusual preference for the oxygen-deficient habitat found at the Angola–Benguela Frontal Zone of the southeastern Atlantic. With a series of incubation experiments with ¹⁵N-labelled nitrate as a tracer in combination with membrane-inlet mass spectrometry, we studied the potential contribution of L. bicuspidatus to nitrate reduction in the upper sediment layer. Our preliminary results suggest that L. bicuspidatus enhances nitrate reduction if the oxygen concentration is sufficiently low. The Lembulus-mediated nitrate reduction rate is then similar to the rate of microbial nitrate reduction in the surrounding sediment.  相似文献   

Helmert方差分量估计在GPS/GLONASS/BDS组合定位权比确定中的应用     

刘金海  涂锐  张睿  张鹏飞  卢晓春 《大地测量与地球动力学》2018,38(6):568-570

因GNSS系统间观测噪声、轨道精度的差异，采用经验权比进行组合定位难以得到最优结果。基于此，在GPS/GLONASS/BDS组合定位中引入Helmert方差分量估计，对GPS/GLONASS/BDS组合单点定位和基线解算中各系统观测值进行合理定权。实验表明，采用该方法确定的伪距观测值最佳权比为5∶1∶1，相位观测值最佳权比为1∶1∶1，有效提高了GPS/GLONASS/BDS组合定位的精度和可靠性。  相似文献